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Organic fluorine content and change during thermal treatmen
Hušek, Matěj
2023 - anglický
We have previously described how pyrolysis affected the content of selected PFAS representatives.4,5 However, we could not determine with certainty whether they were merely cleaved or mineralised. Therefore, we focused on the change in organic fluorine content (part of PFAS) and analysed its thermal behaviour in inert (sea sand) and heterogeneous (sewage sludge) material.
Klíčová slova:
organic fluorine; sewage sludge; thermal treatment
Plné texty jsou dostupné v digitálním repozitáři NUŠL
Organic fluorine content and change during thermal treatmen
We have previously described how pyrolysis affected the content of selected PFAS representatives.4,5 However, we could not determine with certainty whether they were merely cleaved or mineralised. ...
Separation of exosomes from polydisperse suspension in microfluidic devices
Paříková, Anna
2023 - anglický
The work included fine-tuning the experimental methodology, writing an in-house code for exosome tracking based on a one-way\napproach, and performing a parametric study to investigate the separation potential of the microdevice as a function of channel geometry, flow rate, and viscosity. Preliminary results show that viscoelasticmicrofluidics can be used as an alternative to conventional e xosome separation techniques.
Klíčová slova:
separation techniques; exosomes; microfluidic devices
Plné texty jsou dostupné v digitálním repozitáři NUŠL
Separation of exosomes from polydisperse suspension in microfluidic devices
The work included fine-tuning the experimental methodology, writing an in-house code for exosome tracking based on a one-way\napproach, and performing a parametric study to investigate the separation ...
HIGHLY-TIME RESOLVED ELEMENTAL SOURCE APPORTIONMENT OF PM2.5 AT AN URBAN TRAFFIC SITE IN PRAGUE
Windell, Laurence Christian; Pokorná, Petra; Ondráček, Jakub; Schwarz, Jaroslav; Lhotka, Radek; Vodička, Petr; Zíková, Naděžda; Hopke, P.K.; Ždímal, Vladimír
2023 - anglický
This work aims to quantify metal emissions from traffic at an urban traffic site in Prague, Czech Republic, identify key tracers of emissions, and investigate exhaust and non-exhaust emissions observable in fine particulate matter (PM2.5). This project signifies the first high-time resolution elemental analysis of Prague aerosols.
Klíčová slova:
source apportionment; traffic; online
Plné texty jsou dostupné v digitálním repozitáři NUŠL
HIGHLY-TIME RESOLVED ELEMENTAL SOURCE APPORTIONMENT OF PM2.5 AT AN URBAN TRAFFIC SITE IN PRAGUE
This work aims to quantify metal emissions from traffic at an urban traffic site in Prague, Czech Republic, identify key tracers of emissions, and investigate exhaust and non-exhaust emissions ...
INFLUENCE OF RESPIRATORY TRACT CONDITIONS ON PARTICLE SIZE DISTRIBUTIONS GENERATED BY COMMERCIALLY AVAILABLE INHALERS
Mašková, Ludmila; Ždímal, Vladimír; Ondráček, Jakub
2023 - anglický
Pressurized metered dose inhalers (MDI) and dry powder inhalers (DPI) are an integral part of the treatment of lung diseases such as asthma and chronic obstructive pulmonary disease (COPD) (Vichrow et al., 2008). An important characteristic of particles dosed by MDI and DPI is particle size distribution (PSD) (Byron, 1990). This may vary depending on the formulation, but also on the temperature and relative humidity (RH) changes during the transport from the inhaler to the human respiratory tract. The aim of this study was to determine the influence of RH and inspiratory flow rates on the PSD\ncharacteristics and predict deposition efficiency of inhalable particles in the lungs.
Klíčová slova:
number size distribution; inhaler; hygroscopicity
Plné texty jsou dostupné v digitálním repozitáři NUŠL
INFLUENCE OF RESPIRATORY TRACT CONDITIONS ON PARTICLE SIZE DISTRIBUTIONS GENERATED BY COMMERCIALLY AVAILABLE INHALERS
Pressurized metered dose inhalers (MDI) and dry powder inhalers (DPI) are an integral part of the treatment of lung diseases such as asthma and chronic obstructive pulmonary disease (COPD) (Vichrow et ...
ON OUR RECENT WORK IN STUDYING NEW PARTICLE FORMATION (NPF)
Kovářík, Jiří; Špalová, Anna; Roztočil, Petr; Zíková, Naděžda; Schwarz, Jaroslav; Ždímal, Vladimír
2023 - anglický
New particle formation (NPF) is increasingly gaining attention since it emerged roughly twenty years ago as a field of interest within the aerosol science. It studies the transition process between gas phase molecules, forming clusters and eventually becoming aerosol particles. Thus, this field is a multidisciplinary one, ranging from meteorology, atmospheric chemistry and physics, all the way through physical chemistry towards chemistry and physics of aerosols. \nRecent development of instrumentation techniques allows measuring of sub-5 nm particles and molecule clusters, neutral and also charged ones. Therefore, modern analytical methods based on these measurements are often used for NPF studies.
Klíčová slova:
atmospheric aerosols; new particle formation; NAIS
Plné texty jsou dostupné v digitálním repozitáři NUŠL
ON OUR RECENT WORK IN STUDYING NEW PARTICLE FORMATION (NPF)
New particle formation (NPF) is increasingly gaining attention since it emerged roughly twenty years ago as a field of interest within the aerosol science. It studies the transition process between ...
GA 19-07635S: Outputs and Results
Rehák, Branislav
2023 - anglický
This manuscript aims to deliver a survey of results obtained during the solution of the project No. GA19-07635S of the Czech Science Foundation. The timespan dedicated to the work on this project was 1.3.2019 - 30.6.2022. The main area dealt with were\nnonlinear multi-agent systems and their synchronization, further, attention was paid to some auxiliary results in the area of nonlinear observers. This Report briefly introduces the Project, provides a summary of the results obtained and also sketches an outline how these results will be applied and extended in future.
Klíčová slova:
multi-agent systems; nonlinear multi-agent systems; synchronization
Dokument je dostupný na externích webových stránkách.
GA 19-07635S: Outputs and Results
This manuscript aims to deliver a survey of results obtained during the solution of the project No. GA19-07635S of the Czech Science Foundation. The timespan dedicated to the work on this project was ...
Application of In situ TR Spectroelectrochemical Techniques in Determination of Redox Mechanism of Bioactive Compounds
Sokolová, Romana; Jiroušková, Eliška; Degano, I.; Wantulok, J.; Nycz, J.
2023 - anglický
The electron transfer reactions play an important role in many natural processes. Reactions such as \ndissociation, protonation, and reactions with water and other small molecules often occur in \nbiotransformation. The reaction schemes involving these chemical reactions coupled to the \nelectron transfer can be determined by cyclic voltammetry. Additionally, in \nsitu spectroelectrochemistry can efficiently contribute to the determination of oxidation or \nreduction mechanism. This technique provides information about the electroactive chromophore during \nthe redox process allowing to identification the first reaction intermediates. The final reaction \nproducts were identified by chromatographic techniques. This study represents a key role of TR \nspectroelectrochemistry in the determination of reaction intermediates in the case of \n1,10- phenanthroline derivative substituted by bioactive phenothiazine unit and \ndrug 3- fluorophenmetrazine (2-(3-fluorophenyl)-3-methylmorpholine, 3-FPM). Co pound 3-FPM\nhave recently appeared as the new psychoactive substance in the drug market.\n
Klíčová slova:
IR spectroelectrochemistry; psychoactive substances; oxidation mechanism
Plné texty jsou dostupné na vyžádání prostřednictvím repozitáře Akademie věd.
Application of In situ TR Spectroelectrochemical Techniques in Determination of Redox Mechanism of Bioactive Compounds
The electron transfer reactions play an important role in many natural processes. Reactions such as \ndissociation, protonation, and reactions with water and other small molecules often occur in ...
A polarizable reference electrode
Mareček, Vladimír
2023 - anglický
New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly \nhydrophobic common cation between two immiscible electrolyte solutions (TTTES). The use of a \npolarizable metal electrode instead of a classical reference electrode is demonstrated in \n a modified conventional four-electrode cell with TTTES. A simple battery operated potentiostat \ncontrols the working electrode potential in a three-electrode configuration. The working metal \nelectrode then serves as a polarizable reference organic solvent electrode in a four-electrode \nsystem for the polarization of the water/organic solvent interface.\n\n
Klíčová slova:
reference electrode; liquid/liquid interface; chloride extraction
Plné texty jsou dostupné na vyžádání prostřednictvím repozitáře Akademie věd.
A polarizable reference electrode
New concept of a reference electrode for electrochemical systems resolves a problem of a poor \npotential stability of refence electrodes based on the distribution of a strongly ...
Determination of Selected Natural Psychoactive Substances in Organic Matrices at 3D Printed Electrodes
Choińska-Mlynarczyk, Marta; Šestáková, Ivana; Navrátil, Tomáš
2023 - anglický
Psilocybin and its derivative psilocin are popular psychoactive substances both as experimental\ntreatments in clinical trials and as illicit drugs. Their potential ability to influence the human\nbrain entails the need for a fast, inexpensive, selective, and sensitive method of their\ndetermination. The aim of our study was the development of new 3D-printed electrodes which\nfulfill these demands and are useful for medical, toxicological, and forensic purposes.\nSuccessful development allows determining in real matrices (human plasma and dried\nmushrooms) concentrations of the order of 1 μmol dm-3.\n
Klíčová slova:
natural psychoactive substances; 3D-printed electrodes; psilocin; psilocybin
Plné texty jsou dostupné na vyžádání prostřednictvím repozitáře Akademie věd.
Determination of Selected Natural Psychoactive Substances in Organic Matrices at 3D Printed Electrodes
Psilocybin and its derivative psilocin are popular psychoactive substances both as experimental\ntreatments in clinical trials and as illicit drugs. Their potential ability to influence the ...
Dynamics of Machines and Mechanical Systems with Interactions, DYMAMESI 2023
Zolotarev, Igor; Pešek, Luděk; Kozień, M. S.
2023 - anglický
The aim of the DYMAMESI is to facilitate the exchange of up to date information and knowledge among specialists in structural and multibody dynamics, in coupled interacting systems as aero-elasticity, hydro-elasticity, biomechanics, systems with feedbacks and mechatronics. The colloquium DYMAMESI 2021 is cofunded by the Strategy AV21 initiative of the Czech Academy of Sciences of the Czech Republic, and in 2021 will be hosted by Cracow University of Technology, Institute of Applied Mechanics, Section of Dynamics of Systems.
Klíčová slova:
dynamics; vibrations of mechanical systems; vibrodiagnostics; energy transformations
Plné texty jsou dostupné na jednotlivých ústavech Akademie věd ČR.
Dynamics of Machines and Mechanical Systems with Interactions, DYMAMESI 2023
The aim of the DYMAMESI is to facilitate the exchange of up to date information and knowledge among specialists in structural and multibody dynamics, in coupled interacting systems as aero-elasticity, ...
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