Příprava monovrstevných a vícevrstevných katalyzátorů MoS2 pro rozklad H2S
Kaluža, Luděk; Zdražil, Miroslav; Gulková, Daniela; Soukup, Karel
2023 - Czech Byl připraven monovrstevný katalyzátor MoS2/Al2O3 a vícevrstevné (krystalické) katalyzátory MoS2/Al2O3 a MoS2/TiO2. Byly stanoveny základní strukturně-texturní parametry katalyzátorů fyzisorpcí N2 a roentgenovou difrakční analýzou. Monolayer catalyst MoS2/Al2O3 and multilayer (crystalline) catalysts MoS2/Al2O3 and MoS2/TiO2 were prepared. The basic structural-textural parameters of the catalysts were determined by N2 physisorption and X-ray diffraction analysis. Keywords: MoS2 monolayer; crystalline MoS; Al2O3; TiO2 Available at various institutes of the ASCR Příprava monovrstevných a vícevrstevných katalyzátorů MoS2 pro rozklad H2S

Byl připraven monovrstevný katalyzátor MoS2/Al2O3 a vícevrstevné (krystalické) katalyzátory MoS2/Al2O3 a MoS2/TiO2. Byly stanoveny základní strukturně-texturní parametry katalyzátorů fyzisorpcí N2 a ...

Kaluža, Luděk; Zdražil, Miroslav; Gulková, Daniela; Soukup, Karel
Ústav chemických procesů, 2023

24. ročník Školy hmotnostní spektrometrie. KURZ C - Základy proteomiky
Cvačka, Josef; Vlk, Mikuláš; Vrkoslav, Vladimír; Hubálek, Martin
2023 - Czech Keywords: mass spectrometry; proteomics; data analysis Available on request at various institutes of the ASCR 24. ročník Školy hmotnostní spektrometrie. KURZ C - Základy proteomiky

Cvačka, Josef; Vlk, Mikuláš; Vrkoslav, Vladimír; Hubálek, Martin
Ústav organické chemie a biochemie, 2023

Závěrečná zpráva 2023 o výzkumu výsypek v okolí Sokolova na základě dohody mezi ENKI ops a Ústavem půdní biologie a biogeochemie BC AV ČR, v. v. i.
Frouz, Jan; Lišková, K.; Bartuška, Martin; Badraghi, A.; Mudrák, O.; Kučera, J.; Montagnani, L.; Bednářová, E.; Šimáňová, D.; Reinshmidová, E.
2023 - Czech Zpráva přináší souhrn výsledků výzkumu obnovy půd a ekosystémů na území postiženém těžbou nerostů na Sokolovsku na základě dohody mezi ENKI ops a Ústavem půdní biologie a biogeochemie BC AV ČR za rok 2023. The report brings main results of the research about soil and ecosystem recovery in post mining landscape near Sokolov based on agreement between ENKI ops and Institute of soil biology and biogeochemistry, BC CAS. Keywords: final report; research; Sokolov; post mining sites Available at various institutes of the ASCR Závěrečná zpráva 2023 o výzkumu výsypek v okolí Sokolova na základě dohody mezi ENKI ops a Ústavem půdní biologie a biogeochemie BC AV ČR, v. v. i.

Zpráva přináší souhrn výsledků výzkumu obnovy půd a ekosystémů na území postiženém těžbou nerostů na Sokolovsku na základě dohody mezi ENKI ops a Ústavem půdní biologie a biogeochemie BC AV ČR za rok ...

Frouz, Jan; Lišková, K.; Bartuška, Martin; Badraghi, A.; Mudrák, O.; Kučera, J.; Montagnani, L.; Bednářová, E.; Šimáňová, D.; Reinshmidová, E.
Biologické centrum, 2023

Methodology for co-cryostorage of virus isolates in their host plants and relevant data
Bilavčík, A.; Bjerkestrand, R.; Bjelland, B.; Blystad, D.-R.; Bobrova, O.; Fránová, Jana; Faltus, M.; Hamborg, Z.; Hammond Hammond, S. D.; Koloniuk, Igor; Zámečník, J.
2023 - English Currently, the nursery production of plant material emphasizes the production of healthy, virus-free material. For this reason, it is necessary to have reference plant materials in which the virus is present. Some types of viruses are difficult to maintain outside the plant host. Because of the potential transmission to outdoor plantings, it is necessary to keep infected plants in special cultivation areas, and net-houses, which brings considerable financial and labour costs. Therefore, a methodology was developed in which the virus status in plant material is analysed, the infected material can be stored using cryopreservation in liquid nitrogen and then regenerated in vitro, and relevant data in GeneEver cryobox can be stored. Keywords: genetic resources; virus; Rubus idaeus L. Fulltext is available at external website. Methodology for co-cryostorage of virus isolates in their host plants and relevant data

Currently, the nursery production of plant material emphasizes the production of healthy, virus-free material. For this reason, it is necessary to have reference plant materials in which the virus is ...

Bilavčík, A.; Bjerkestrand, R.; Bjelland, B.; Blystad, D.-R.; Bobrova, O.; Fránová, Jana; Faltus, M.; Hamborg, Z.; Hammond Hammond, S. D.; Koloniuk, Igor; Zámečník, J.
Biologické centrum, 2023

Detailed Investigation of Human Galectins -1 and -3 by employing selectively deoxyfluorinated N-acetyllactosamines
Kurfiřt, Martin
2023 - English This work is focused on a detailed investigation of supramolecular recognition events between human galectins -1 and -3 and monodeoxyfluorinated N-acetyllactosamine probes, which were previously prepared in our laboratory. The recognition was studied using a combination of X-ray crystallography, isothermal titration calorimetry and several advanced NMR techniques, such as 19F T2-filter, 1H–1H STD, 1H–15N CSP or 19F EXSY. These techniques provided insight into the thermodynamics and kinetics of recognition and enabled us to uncover of subtle differences between both investigated galectins. Such differences could be potentially exploited in the selective targeting of individual galectins with important implications for the galectins-focused\npharmaceutic industry. Keywords: galectins; NMR techniques; pharmaceutic industry Available in a digital repository NRGL Detailed Investigation of Human Galectins -1 and -3 by employing selectively deoxyfluorinated N-acetyllactosamines

This work is focused on a detailed investigation of supramolecular recognition events between human galectins -1 and -3 and monodeoxyfluorinated N-acetyllactosamine probes, which were previously ...

Kurfiřt, Martin
Ústav chemických procesů, 2023

The electrodiffusional theory for wall shear stress measurement by a two-strip probe: a journey to near-wall region hydrodynamics
Harrandt, Václav
2023 - English This contribution deals with a new theory describing mass transport in the vicinity of the measuring two-segment strip probe. Analytical formulas for the mass transfer coefficients of the front and the rear electrodes were derived. At the same time, the correctness of these formulas was confirmed by the numerical solution of the convectiondiffusion transport equation. Keywords: transport phenomena; electrodes; wall shear stress Available in a digital repository NRGL The electrodiffusional theory for wall shear stress measurement by a two-strip probe: a journey to near-wall region hydrodynamics

This contribution deals with a new theory describing mass transport in the vicinity of the measuring two-segment strip probe. Analytical formulas for the mass transfer coefficients of the front and ...

Harrandt, Václav
Ústav chemických procesů, 2023

(NE)ZÁVISLOST AKTIVACE AEROSOLU NA POZICI V OBLAKU
Zíková, Naděžda; Pokorná, Petra; Sedlák, Pavel; Sokol, Zbyněk; Ždímal, Vladimír
2023 - Czech Na hoře Milešovka v České republice bylo provedeno pět in situ kampaní zaměřených na interakci aerosolu s oblakem, jejichž cílem bylo získat více informací o aktivaci aerosolu a její závislosti na meteorologických parametrech, především vertikální rychlosti proudění vzduchu a poloze v oblaku. Aktivovaná frakce byla vypočtena z rozdílu koncentrací naměřených za vtokem celého vzduchu a za vtokem PM2,5 . Obsah kapalné vody (LWC) byl vypočten z dohlednosti, poloha základny mraku byla odhadnuta z údajů ceilometru. Vertikální rychlost proudění vzduchu byla odhadnuta z radarového měření oblačnosti. Nebyla zjištěna žádná silná závislost mezi dohledností a vertikální rychlostí, což naznačuje, že oblačnost na stanici je většinou advekčního nebo inverzního původu. Viditelnost i LWC závisí na poloze v oblaku, přičemž nejvyšší hodnoty LWC byly zjištěny, když se stanice nacházela ve výšce 100 až 400 m nad základnou oblaku, nezávisle na skutečné hodnotě. Five in situ campaigns focused on aerosol-cloud interactions were conducted at Mount Milešovka in the Czech Republic to gain more insight into aerosol activation and its dependence on meteorological parameters, mainly vertical air velocity and position within the cloud. The activated fraction was calculated from the difference of concentrations measured behind the whole air inlet and the PM2.5 inlet. The liquid water content (LWC) was calculated from visibility, cloud base position was estimated from ceilometer data. Vertical air velocity was estimated from cloud radar. No strong dependence was found between visibility and vertical velocity, suggesting that the clouds at the station are mostly of advection or inversion origin. Both visibility and LWC depend on the position within the cloud, with the highest LWC values found when the station was between 100 and 400 m above the cloud base, independently of the actual value. Keywords: atmospheric aerosols; activation; cloud base Available in a digital repository NRGL (NE)ZÁVISLOST AKTIVACE AEROSOLU NA POZICI V OBLAKU

Na hoře Milešovka v České republice bylo provedeno pět in situ kampaní zaměřených na interakci aerosolu s oblakem, jejichž cílem bylo získat více informací o aktivaci aerosolu a její závislosti na ...

Zíková, Naděžda; Pokorná, Petra; Sedlák, Pavel; Sokol, Zbyněk; Ždímal, Vladimír
Ústav chemických procesů, 2023

3D Printed Microfluidic Cell for Spectroelectrochemical Analysis
Šikula, M.; Vaněčková, Eva; Hromadová, Magdaléna; Kolivoška, Viliam
2023 - English Recent advances in fused deposition modeling 3D printing (FDM 3DP) enabled \nthe manufacture of customized spectroelectrochemical (SEC) devices. Despite significant progress, \nreported designs still rely on conventional optical components (windows and cuvettes). In this \nwork, we apply bi-material FDM 3DP combining electrically conductive and optically \ntranslucent filaments to manufacture a fully integrated microfluidic SEC device. Employing cyclic \nvoltammetric measurements with redox probes, we demonstrate that the platform allows SEC sensing of \nreactants, intermediates, and products of charge transfer reactions in an oxygen- free \nenvironment. Developed approaches pave the way for SEC d vices with dramatically\nreduced costs compared to currently available commercial platforms.\n Keywords: spectroelectrochemistry; three-dimensional printing; fused deposition modeling Available on request at various institutes of the ASCR 3D Printed Microfluidic Cell for Spectroelectrochemical Analysis

Recent advances in fused deposition modeling 3D printing (FDM 3DP) enabled \nthe manufacture of customized spectroelectrochemical (SEC) devices. Despite significant progress, ...

Šikula, M.; Vaněčková, Eva; Hromadová, Magdaléna; Kolivoška, Viliam
Ústav fyzikální chemie J. Heyrovského, 2023

Electrochemical Properties of Mixed Self-Assembled Monolayers Based on Terpyridine Transition Metal Complexes
Kocábová, Jana; Nováková Lachmanová, Štěpánka; Vavrek, František; Valášek, M.; Hromadová, Magdaléna
2023 - English This work presents the electrochemical characterization of mixed self-assembled monolayers\n(SAMs) of [Os(terpy)2]2+ and terpyridine connected by tripodal anchoring groups to the\npolycrystalline gold bead electrode and provides a comparison with SAM based on\n[Os(terpy)2]2+ tripodal molecules without diluting terpyridine tripodal molecules. It is shown\nthat both arrangements enable reproducible preparation of well-defined compact films. The\nelectron transfer rate constant for mixed SAM was determined from cyclic voltammograms\naccording to Laviron’s analysis and compared with the rate constant obtained previously for\nSAM containing only [Os(terpy)2]2+ tripod. Keywords: transition metal complexes; terpyridine; tripodal anchor Available on request at various institutes of the ASCR Electrochemical Properties of Mixed Self-Assembled Monolayers Based on Terpyridine Transition Metal Complexes

This work presents the electrochemical characterization of mixed self-assembled monolayers\n(SAMs) of [Os(terpy)2]2+ and terpyridine connected by tripodal anchoring groups to the\npolycrystalline gold ...

Kocábová, Jana; Nováková Lachmanová, Štěpánka; Vavrek, František; Valášek, M.; Hromadová, Magdaléna
Ústav fyzikální chemie J. Heyrovského, 2023

Elimination Voltammetry with Linear Scan: Advantages and Disadvantages
Navrátil, Tomáš; Trnková, L.; Hrdlička, Vojtěch; Li, X.
2023 - English Elimination voltammetry with linear scan (EVLS) represents an almost traditional\nmathematical method that helps to obtain additional and detailed information about the recorded\nelectrochemical signals and therefore, to better understand the analyzed systems. Although it\nhas been substantially developed and expanded during its existence of more than a quarter of a\ncentury and has found many areas of application, like any other mathematical and experimental\nmethod, it exhibits several advantages and disadvantages. In this contribution, we summarize\nits strengths, weaknesses, opportunities, as well as threats.\n Keywords: elimination voltammetry with linear scan; advantages; disadvantages Available on request at various institutes of the ASCR Elimination Voltammetry with Linear Scan: Advantages and Disadvantages

Elimination voltammetry with linear scan (EVLS) represents an almost traditional\nmathematical method that helps to obtain additional and detailed information about the recorded\nelectrochemical ...

Navrátil, Tomáš; Trnková, L.; Hrdlička, Vojtěch; Li, X.
Ústav fyzikální chemie J. Heyrovského, 2023